Chapter 2 MINERALS


A. DEFINITION

B. CHEMISTRY

C. PHYSICAL PROPERTIES

D. CHEMICAL PROPERTIES

E. SILICATE MINERALS

F. OTHER MINERALS

G. BIRTHSTONES

H. MINERAL RESOURCES

I. STATE MINERAL & GEM

J. MINERALS TO KNOW

K. PRACTICE QUESTIONS

L. VIDEOTAPE

 

 Beryl and pyrite on quartz


Minerals are the fundamental building blocks of the Earth and make up rocks, which have recorded the history of the Earth. Minerals and rocks are essential for human existence; all of our resources are derived from rocks/minerals or from living things that depend on rocks/minerals/soil. In addition, minerals are used for investment and jewelry.


 KEY TO MINERAL SETS

Chemical

Group

Mineral

Name

Specimen

Number

Chemical

Composition

Silicate

Type

Chloride

 halite

(11)

 NaCl

  

Sulfides

 sphalerite

(3)

 ZnS

  

 

 galena

(4)

 PbS

  

 

 pyrite

(5)

 FeS2

  

Oxides

 hematite

(1)

 Fe2O3

  

 

 limonite

(2)

 Fe2O3·nH2O

  

Carbonates

 calcite

(9)

 CaCO3

  

Sulfate

 gypsum

(8)

 CaSO4·2H2O

  

Silicates

 olivine

(18)

 Fe, Mg, Si, O

 single

 

 augite

(17)

 Ca, Fe, Mg, Si, O

 chain

 

 hornblende

(16)

 Ca, Fe, Mg, Al, Si, O, H2O

 chain

 

 muscovite

(14)

 K, Al, Si, O, H2O

 sheet

 

 biotite

(15)

 K, Fe, Mg, Al, Si, O, H2O

 sheet

 

 kaolinite

(10)

 Al, Si, O, H2O

 sheet

 

 quartz

(7)

 SiO2

 3-D

 

 Feldspar

(12, 13)

 K, Na, Ca, Al, Si, O

 3-D


1. HEMATITE - earthy variety called "red ocher"

Composition: Fe2O3

Diagnostic features:

Streak: reddish-brown

Luster: earthy

(Other properties vary widely.)

Occurrence: formed under a wide variety of conditions and associated with the main kinds of rocks.

Use: most important ore of iron, red pigment, polishing powder.

Name: from a Greek word meaning blood.

 

HEMATITE - specular variety, with metallic luster.

Composition: Fe2O3

Diagnostic features:

Streak: reddish-brown

Luster: metallic

(Other properties vary widely.)

Occurrence: formed under a wide variety of conditions and associated with the three kinds of rocks.

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2. LIMONITE - yellow ocher

Composition: Fe2O3·nH2O

Diagnostic features:

Streak: yellow-brown

(Other properties vary widely.)

Occurrence: formed by alteration of previously existing iron minerals.

Use: pigment, minor source of iron

Name: from a Greek word meaning meadow, in allusion to its occurrence in bogs.

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3. SPHALERITE

Composition: ZnS

Diagnostic features:

Color: yellow to brown and black

Hardness: 3.4 to 4

Chemical test: powder is decomposed in hydrochloric acid with evolution of hydrogen sulfide gas.

Streak: light yellow to white

Occurrence: in igneous rocks and in veins in limestone; associated with galena, pyrite, and fluorite.

Use: the most important ore of zinc.

Name: from the Greek word meaning treacherous or uncertain, because it resembles galena but yields no lead.

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4. GALENA

Composition: PbS (almost always contains silver.)

Diagnostic features:

Color: lead gray

Hardness: 2.5

Specific gravity: 7.5 (heavy)

Luster: metallic

Cleavage: cubic

Occurrence: in igneous rocks and in veins in limestone, associated with sphalerite and fluorite.

Use: practically the only source of lead and an important ore of silver.

Name: from the Latin word meaning lead ore.

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5. PYRITE

Composition: FeS2

Diagnostic features:

Color: brass yellow (fool's gold)

Hardness: 6 to 6.5 (hardness of gold is 2.5 to 3)

Streak: greenish-black or brownish-black.

Crystal form: cubic crystals are sometimes observed, bearing parallel striations.

Occurrence: found in all three kinds of rocks.

Use: in manufacture of sulfuric acid.

Name: from the Greek word meaning fire, in allusion to the fact that when struck with steel it gives off brilliant sparks.

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6. CHALCOPYRITE

Composition: CuFeS2

Diagnostic features:

Color: brass yellow, but often tarnished to bronze or iridescent.

Hardness: 3.5 to 4 (less than pyrite).

Streak: greenish-black

Crystal form: usually massive, crystals not observed.

Occurrence: usually found in veins in igneous rocks.

Use: the most widely occurring copper mineral and one of the most important sources of copper.

Name: derived from the Greek word meaning copper and from pyrite.

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7. QUARTZ

Composition: SiO2

Diagnostic features:

Hardness: 7

Luster: glassy

Conchoidal fracture (no cleavage)

(May or may not occur as crystals.)

Occurrence: next to feldspar, the most abundant mineral of the Earth's crust; found in all three kinds of rocks.

Use: radio and radar "crystals", ornamental, manufacture of glass and many other uses.

Name: the name quartz is a German word of ancient derivation.

 

QUARTZ - rose variety

This is another variety of quartz.

Some others: amethyst, citrine, cat's eye, rock crystal (hexagonal crystals).

 

QUARTZ - variety called chert.

This is still another variety of quartz; but in this variety, the crystals are too fine to be seen. It is similar to flint, but is light in color rather than dark. It is found mainly in sedimentary rocks.

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8. GYPSUM - variety "rock gypsum" occurs in granular masses.

Composition: CaSO4·2H2O

Diagnostic features:

Color: light colored or transparent

Hardness: 2 (can be scratched with fingernail)

Occurrence: commonly found in sedimentary rocks; formed under evaporitic conditions.

Use: Plaster of Paris, gypsum lath, fertilizer, ornamental (variety called alabaster).

Name: from the Greek word (name) for the mineral.

 

GYPSUM - variety "selenite gypsum" is found in crystalline form.

Compared with muscovite (#14), selenite gypsum is softer and cleaves into tabular plates which can be bent but are not elastic as are muscovite and biotite.

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9. CALCITE

Composition: CaCO3

Diagnostic features:

Color: usually colorless to white, but other colors occur.

Hardness: 3

Cleavage: good along three inclined planes.

Chemical test: effervesces freely in cold, dilute hydrochloric acid.

Occurrence: chief constituent of limestone, chalk, and marble.

Use: chiefly in manufacture of cement, also decorative, and in optical instruments.

Name: from the Latin word calx meaning burnt lime.

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10. KAOLINITE

Composition: hydrous aluminum silicate.

Diagnostic features:

Color: white

Feel: greasy

Smell: earthy

Found in small masses.

Note: does not react to acid, as does the rock chalk.

Occurrence: results from the alteration of other aluminum silicates, particularly feldspar.

Use: paper, china, brick.

Name: kaolinite is derived from kaolin, which is a corruption of the Chinese word kauling meaning high ridge, the name of a hill near Jauchu Fa where the mineral is obtained.

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11. HALITE

Composition: NaCl

Diagnostic features:

Hardness: 2.5

Cleavage: cubic

Taste: salty

Feel: "damp"

Soluble in water

Occurrence: precipitated from sea water under evaporitic conditions and found in sedimentary rocks.

Use: common table salt; source of sodium.

Name: from the Greek word meaning salt.

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12. ORTHOCLASE FELDSPAR

Composition: KAlSi3O8

Diagnostic features:

Hardness: 6

Color: usually pink or white

Luster: vitreous

Cleavage: two good at 90°

Occurrence: orthoclase and the other feldspars are the most abundant minerals in the Earth's crust; found in all three kinds of rocks but most commonly in igneous rocks.

Use: in manufacture of porcelain.

Name: orthoclase refers to the right angle cleavage; feldspar is derived from the German word feld meaning field.

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13. PLAGIOCLASE FELDSPAR - The term "plagioclase feldspar" refers to a continuous gradational series of minerals which range in chemical composition from pure sodic plagioclase, called albite, to pure calcic plagioclase, called anorthite.

Composition: NaAlSi3O8 to CaAl2Si2O8

Diagnostic features:

Color: white to gray

Hardness: 6

Luster: vitreous

Cleavage: two good at approximately 94°.

Occurrence: found in igneous, metamorphic, and more rarely in sedimentary rocks.

Use: in ceramics, semi-precious stones.

Name: from the Greek word meaning oblique in allusion to the oblique angle between the cleavage planes.

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14. MUSCOVITE MICA

Composition: complex hydrous potassium aluminum silicate.

Diagnostic features:

Color: colorless to white or silvery

Cleavage: one perfect

Large flakes are elastic

Occurrence: characteristic of igneous rocks and also found in metamorphic and sedimentary rocks.

Use: electrical insulation, heat insulation.

Name: Muscovite was so called from the popular name of the mineral muscovy glass, because of its use as a glass substitute in Muscovy. Mica was probably derived from the latin micare meaning to shine.

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15. BIOTITE MICA

Composition: complex hydrous potassium iron magnesium aluminum silicate.

Diagnostic features:

Color: dark green brown, black

Cleavage: one perfect

Large flakes are elastic

Occurrence: same as muscovite

Name: in honor of the French physicist, J. B. Biot.

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16. HORNBLENDE - One of a number of similar minerals collectively referred to as the amphibole group.

Composition: complex hydrous calcium magnesium iron aluminum silicate.

Diagnostic features:

Color: dark green to black

Hardness: 5 to 6

Cleavage: two at angles of 56° and 124°

Crystals: frequently prismatic

Occurrence: in igneous rocks and metamorphic rocks.

Name: from an old German word for any dark prismatic mineral occurring in ores but containing no metal.

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17. AUGITE - One of a number of similar minerals collectively referred to as the pyroxene group.

Composition: complex calcium magnesium iron silicate.

Diagnostic features:

Hardness: 5 to 6

Cleavage: two at angles of 87° and 93°.

Crystals: short, prismatic

Occurrence: in igneous and metamorphic rocks.

Name: from the Greek word meaning luster.

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18. OLIVINE

Composition: (Mg, Fe)2SiO4

Diagnostic features:

Color: olive green to black

Hardness: (of individual, separate grains) 6.5 to 7.

Luster: vitreous

Occurrence: found mainly in igneous rocks.

Use: as the semi-precious gem peridot.

Name: from olive green color.

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Index

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